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Ultrafast studies of metal-metal bond cleavage in Fe3(CO)12 in solution

โœ Scribed by N.J. Tro; J.C. King; C.B. Harris

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
267 KB
Volume
229
Category
Article
ISSN
0020-1693

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Femtochemistry of organometallics: dynam
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โœ Sang Kyu Kim; Soren Pedersen; Ahmed H. Zewail ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 699 KB

We report femtochemical studies of the organometallic dimetal decacarbonyl. By the use of mass spectrometry, we obtain the temporal dynamics in the channels for metal-metal and metal-ligand bond cleavage. The time scale observed for cleavage and for structural bridging indicates the nature of the re