Photo-transformation of G, C,,,, C,O, and C,Os in toluene results in destruction of these species. CW and CT0 are transformed with equal rates to form C,O and C,OO. No higher oxides of these fullerenes are formed. C,O is destroyed twice as fast and &,,02 approximately 40-50 times faster than Cs Prod
Ultrafast relaxation of excitons and photopolymerization in C60 and C70
โ Scribed by A. Nakamura; M. Ichida; T. Yajima; H. Shinohara; Y. Saitoh
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 548 KB
- Volume
- 66-67
- Category
- Article
- ISSN
- 0022-2313
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The published "C NMR spectra of CGO give an absolute carbon shielding of u=43 ppm, i.e. 14 ppm less than for carbon in benzene. Extrapolation from ab initio coupled Hartree-Fock calculations with the origin of the vectoi potential at the nucleus gives a-46 ppm as the basis-set limit. Minimal basis a
The electronic and vibrational structures of C,, and C,,, have been calculated at the PM3 semiempirical level. C, has a partially delocalized structure, while C,, has both a localized set and a delocalized set of MOs. As with AM1 and MNDO, PM3 predicts the heat of formation of C,, to be greater than