Ultrafast overtone excitation for the study of vibrational population decay in liquids
โ Scribed by H. Graener; A. Laubereau
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 444 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
1 hc v = 2 \t.btc' of 11x Cli-stretching_ mode V~ of CHBr3 is directly popuhted by overtone absorption of XI infrared picowxond pulw. 1 hc IIIIIC aolutlons of the u = Z .md u = 1 lcvci populationsare followed by anti-Stokes Raman probe swttermu. 1 \pcrin~cnr.tl rcwlr~ arc Presented on popularion lifetimes and vibrational energy transfer and compared nit11 model c,dculJtion\ h.wd on spcctrowoprc data
๐ SIMILAR VOLUMES
Two theoretical models for the interpretation of the existing data of CH-stretching overtones' vibrational circular dichroism data are presented. The first model is based on the quantum mechanical Van Vleck contact transformation theory and is applied to the full vibrational problem, the second is b
A dramsr rL'ductton In tnirarcd tluor~~c~nLcqu~ntum gtcld a~th mcrcwn, 0 molucul.tr wc 1s obscrrcd tor dtrcctl) cl- cwd tirst CII strerch ove~~oncs m a scncs of CI -CJ hydrocdrbons Lthmc and Iargr mokuks (Pvth > 15 CIJILY cm-' ) appear to undergo rapid inlramolccular rclxnton wtthm the 1 ps dctcctor