Ultrafast nonadiabatic photodissociation dynamics of F2in solid Ar
β Scribed by M. Sukharev; A. Cohen; Robert Benny Gerber; Tamar Seideman
- Book ID
- 110208384
- Publisher
- Springer
- Year
- 2009
- Tongue
- English
- Weight
- 496 KB
- Volume
- 19
- Category
- Article
- ISSN
- 1054-660X
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π SIMILAR VOLUMES
New ab initio calculations are reported that indicate Art is a linear, asymmetric, C, molecule with equilibrium bond lengths R, ~2.47 A and R2= 2.73 A. The potential energy surface is very shallow along the asymmetric stretch coordinate indicating excursions of the least bound argon atom of 0.5 to 0
A quantum/classical hybrid model is developed for the photodissociation and recombination dynamics of an 12 molecule in low temperature matrix Ar. This simplified model consists of an 12 molecule embedded in a linear chain of Ar atoms. The dynamics of 12 on its A state is treated quantum mechanicall