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Ultrafast nonadiabatic photodissociation dynamics of F2in solid Ar

✍ Scribed by M. Sukharev; A. Cohen; Robert Benny Gerber; Tamar Seideman


Book ID
110208384
Publisher
Springer
Year
2009
Tongue
English
Weight
496 KB
Volume
19
Category
Article
ISSN
1054-660X

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πŸ“œ SIMILAR VOLUMES


On the structure and photodissociation d
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New ab initio calculations are reported that indicate Art is a linear, asymmetric, C, molecule with equilibrium bond lengths R, ~2.47 A and R2= 2.73 A. The potential energy surface is very shallow along the asymmetric stretch coordinate indicating excursions of the least bound argon atom of 0.5 to 0

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A quantum/classical hybrid model is developed for the photodissociation and recombination dynamics of an 12 molecule in low temperature matrix Ar. This simplified model consists of an 12 molecule embedded in a linear chain of Ar atoms. The dynamics of 12 on its A state is treated quantum mechanicall