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Ultrafast isomerization dynamics of retinal in bacteriorhodopsin as revealed by femtosecond absorption spectroscopy

✍ Scribed by Wu, YiShi ;Zhong, Sheng ;Ai, XiCheng ;Hu, KunSheng ;Zhang, JianPing


Book ID
107368467
Publisher
Elsevier
Year
2008
Tongue
English
Weight
591 KB
Volume
53
Category
Article
ISSN
2095-9273

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We have investigated the ultrafast dynamics of trans-1,3,5-hexatriene in cyclohexane and acetonitrile solutions following photoexcitation to the 1 1B u state. The transient absorption in the visible region consists of an instantaneous rise (< 150 fs) and decay in less than 500 fs, whose time constan