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Ultrafast Excited-State Dynamics Preceding a Ligand Trans−Cis Isomerization of f ac -[Re(Cl)(CO) 3 ( t -4-styrylpyridine) 2 ] and f ac -[Re( t -4-styrylpyridine)(CO) 3 (2,2‘-bipyridine)] +

✍ Scribed by Busby, Michael; Matousek, Pavel; Towrie, Michael; Vlček, Antonín


Book ID
121316726
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
268 KB
Volume
109
Category
Article
ISSN
1089-5639

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trans–cis Photoisomerization of the Styr
✍ Julien Bossert; Chantal Daniel 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 274 KB 👁 1 views

## Abstract The __trans‐cis__ isomerization of the styrylpyridine carbon–carbon double bond induced by visible light irradiation in __fac__‐[Re(CO)~3~(bpy)(stpy)]^+^ (bp__y__ = 2,2′‐bipyridine; stpy = __t__‐4‐styrylpyridine) has been investigated by means of quantum‐chemical methods. The structures