Ultrafast time-resolved spectroscopic methods have been used to probe the dynamics associated with ligand-field excited states in complexes of Cr III and Fe II . In the former case, Cr(acac) 3 (where acac is the monodeprotonated form of acetylacetonate) serves as a prototype for studying the 4 T 2 β
Ultrafast excited-state dynamics of ferrocene-bridge-acceptor system
β Scribed by Omar F. Mohammed; Abdelwareth A.O. Sarhan
- Book ID
- 108089202
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 645 KB
- Volume
- 372
- Category
- Article
- ISSN
- 0301-0104
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The process of intramolecular charge separation was studied in three nearly identical donor-bridge-acceptor compounds (1-3) under jet-cooled conditions. Each consists of a vinylcyanonaphthalene group as a powerful electron acceptor and an anilino derivative as an electron donor, separated by a rigid