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Ultrafast dynamics of electronic excitations in semiconductors

✍ Scribed by Thomas Elsaesser; Alfred Leitenstorfer; Tilmann Kuhn; Fausto Rossi


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
460 KB
Volume
33
Category
Article
ISSN
0960-8974

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✦ Synopsis


Coherent nonlinear i)olarizatio,,s and ,~on-equilil)rium distributions of hot (,h,ctro,,s are stu died in t}'nfl.ose(;on(1 (!xt)(~rim(~ilt.s with bulk GaAs. Itolh excito,fic m,(I Ir,,('-ca.r,i(', (;ore l)onents contril)ute to the third or(let polarizatioll (:los(! to the I)ml(lg~p and show a (listinctly (li[[}~rent tim(, I)cllavior. l)hase r(qa.xation during the femtosccond photog(m(,ra.tion process lc~uls to a signi[icant broadeniug of the iuitiM carrier distribution in comparison to the power N)e(trum ol" the optical pulses. The eXl)erim(mtal .csults a.lC ill cxc(4l(,nt agI'COlll(~II[, with a Monte (',ark) sohflion of the semiconductor Bloch equations.


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Ultrafast time-resolved spectroscopic methods have been used to probe the dynamics associated with ligand-field excited states in complexes of Cr III and Fe II . In the former case, Cr(acac) 3 (where acac is the monodeprotonated form of acetylacetonate) serves as a prototype for studying the 4 T 2 β†’