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Ultra-fast microwave enhanced reversible addition-fragmentation chain transfer (RAFT) polymerization: monomers to polymers in minutes

✍ Scribed by Brown, Steven L.; Rayner, Christopher M.; Graham, Susan; Cooper, Andrew; Rannard, Steven; Perrier, S?bastien

Book ID: 115531058
Publisher: Royal Society of Chemistry
Year: 2007
Tongue: English
Weight: 192 KB
Volume: 21
Category: Article
ISSN: 1359-7345
DOI: 10.1039/b703386a

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## Abstract **Summary:** A detailed investigation of chain transfer to polymer during free radical ring‐opening polymerization of the eight‐membered disulfide monomer 2‐methyl‐7‐methylene‐1,5‐dithiacyclooctane (MDTO) is presented. It has been shown that extensive chain transfer to polymer occurs in