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UHV adsorption studies of K/H2O on Pt(111) and O/CH3COOH on Cu(110): orientation and intermediates

✍ Scribed by P. Baumann; G. Pirug; D. Reuter; H.P. Bonzel

Book ID
116067344
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
929 KB
Volume
335
Category
Article
ISSN
0039-6028

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By coadsorbing hydrogen and water on Pt( 111) and Cu( I lo), and isotopically substituting (H),.,by (D)ad, we have unambiguously identified the occurrence of the electrochemical reaction (H)ad+ (H\*O),,~(H,O+),+e,,,, in UHV. On Pt( I I1 ), a substantial fraction of the hydrogen is oxidized to (H,O+)