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Two products from the reaction of dipyridylamine with [Cu(sac)2(H2O)4]·2H2O, including the first example of a mononuclear transition metal complex with both N- and O-bonded saccharinate ligands

✍ Scribed by Robert M.K. Deng; Keith B. Dillon; Andrés E. Goeta; Mmilili Mapolelo

Publisher: Elsevier Science
Year: 2001
Tongue: English
Weight: 102 KB
Volume: 315
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(01)00336-x

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✦ Synopsis

The crystal and molecular structures of the five-coordinate complexes [Cu(dipyr

have both been determined; the monosubstituted product represents the first example of a mononuclear transition metal complex with N-and O-bonded saccharinate ligands present, both at comparatively short distances from Cu.

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