Two Polymeric Complexes of Norfloxacin with Iron(II) and Their Magnetic Properties

✍ Scribed by Zhi-Rong Qu; Hong Zhao; Li-Xin Xing; Xi-Sen Wang; Zhen-Feng Chen; Zhi Yu; Ren-Gen Xiong; Xiao-Zeng You

• Publisher: John Wiley and Sons
• Year: 2003
• Tongue: English
• Weight: 150 KB
• Volume: 2003
• Category: Article
• ISSN: 1434-1948
• DOI: 10.1002/ejic.200300242

✦ Synopsis

Abstract

The reaction of H‐Norf with (NH~4~)~2~Fe(SO~4~)~2~·6H~2~O and Fe(OH)~3~ (or Fe~2~O~3~) affords Fe(H‐Norf)~2~(SO~4~)·2H~2~O (1) and Fe(Norf)~2~·4H~2~O (2), respectively, both of which have 2D polymeric structures. Their interesting magnetic properties are also reported. Crystal data for 1: monoclinic, __P__2~1~/c, a = 23.166(1), b = 10.0492(4), c = 7.7264(3) Å, β = 98.379(1)°, V = 1779.50(13) Å^3^, Z = 2; for 2: monoclinic, __P__2~1~/c, a = 5.8411(12), b = 21.685(4), c = 13.265(3) Å, β = 99.20(3)°, V = 1658.6(6) Å^3^, Z = 2. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)