Chain scission induced by two-photon exposure produces a permanent birefringence in polysilane polymer films, which can be used for the formation of birefringent optical elements. Spectroscopy of the effect for poly( di-n-hexylsilane) reveals an unexpected sharp resonance at 580 nm. A comparison of
β¦ LIBER β¦
Two-photon spectroscopy of polysilanes
β Scribed by J.R.G. Thorne; Y. Ohsako; J.M. Zeigler; R.M. Hochstrasser
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 508 KB
- Volume
- 162
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
We report the first twephoton excited fluorescence excitation spectra for polysilanes in solution, film, and low temperature glass. We discuss band-teband and exciton models for the optical excitations, in order to explain a strong two-photon resonance 0.9 eV above the first absorption band.
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