The two-phonon Raman spectra of solid argon at 60 K, 22.1 cm 3/mole and at I53.5K, 22.3 cm3/mole are calculated, with phonon frequencies obtained from a calculation in which cubic anharmonicity is included self-consistently and short-range correlations are incorporated. The results are compared with
Two-phonon Raman scattering of light in argon at low temperatures
β Scribed by J. G. Leese; G. K. Horton; E. R. Cowley
- Publisher
- Springer US
- Year
- 1979
- Tongue
- English
- Weight
- 346 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0022-2291
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β¦ Synopsis
The two-phonon Raman spectrum of solid argon at 19 K has been calculated using the point-dipole model, with phonon frequencies derived from a model fitted to neutron scattering experiments. The positions of peaks in the calculated spectra correlate well with peaks in the measured results. In order to obtain correctly the sharpness of the peaks it is necessary to include a small linewidth in the phonon spectral[unctions. Some discrepancies remain, which may show the inadequacy of the point-dipole matrix element, assuming that the correction of the data for background, etc. is reliable.
*Work submitted in partial fulfillment of the requirements of the Ph.D. degree at Rutgers University.
π SIMILAR VOLUMES
In this paper we calculate the two-phonon efficiency for light scattering from rare gas crystals at all temperatures. We use a Lennard-Jones potential and.the Lorentz-Lorenz model following previous theoretical work and use the firstorder self-consistent phonon theory, supplemented by a simple model
## Abstract The Raman spectra of GeS single crystals are investigated in the temperature interval 20 to 300 K. The possible origin of new features observed at low temperatures is discussed. A new assignment of the offβdiagonal B~1g~ and B~3g~ modes is proposed.