Two new copper-FOX-7 complexes: synthesis, crystal structure, and thermal behavior
β Scribed by He, Fei; Xu, Kang-Zhen; Zhang, Hang; Qiu, Qian-Qian; Song, Ji-Rong; Zhao, Feng-Qi
- Book ID
- 127000334
- Publisher
- Taylor and Francis Group
- Year
- 2013
- Tongue
- English
- Weight
- 547 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0095-8972
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Two new organic monophosphates, C3H12N 2Ψ 2 β’ HPO 2Ψ 4 β’ H2O (DAPHP) and C6H18N 2Ψ 3 β’ 2HPO Ψ 4 β’ 4H2O (TMEDH2P), are obtained by action of H3PO4 with respectively 1,2-diaminopropane and N,N,N,N-tetramethylethylenediamine. DAPHP is monoclinic, P21/n, with a β«Ψβ¬ 10.653(3) A s , b β«Ψβ¬ 6.025(1) A s , c
## Abstract The reaction of Cu(AcO)~2~ Β· H~2~O and tridentate Ξ²βiminoketone ligands yielded four new copper complexes: acetato{4β{[2β(dimethylamino)ethyl]amino}pentβ3βenβ2βonato}copper(II) (1), triacetato{4β{[3β(dimethylamino)βpropyl]amino}pentβ3βenβ2βonato}dicopper(II) (2), {4β{[2β(dimethylamino)e
## Abstract The reaction of copper(I) chloride with acetonethiosemicarbazone (tscac) in a copper to tscac molar ratio of 1:2 forms the cationic complex [Cu(tscac)~2~]Cl (1). When the ratio of the copper to tscac was reduced to 1:1, a dimeric complex [Cu~2~Cl~2~(tscac)~2~]~2~ (2) was obtained. In co