𝔖 Bobbio Scriptorium
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Two-electron atomic systems confined within spheroidal boxes

✍ Scribed by A. Corella-Madueño; R. A. Rosas; J. L. Marín; R. Riera

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
393 KB
Volume
77
Category
Article
ISSN
0020-7608

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✦ Synopsis

The direct variational method is used to estimate some interesting physical properties of the He atom and the Li + ion confined within impenetrable spheroidal boxes. A comparative investigation of the ground-state energy, pressure, polarizability, dipole, and quadrupole moments with those of the He atom inside boxes with paraboloidal walls is made. The overall results show a similar qualitative behavior. However, for Li + there are quantitative differences on such properties due to its major nuclear charge, as expected. The trial wave function is constructed as a product of two hydrogenic wave functions adapted to the geometry of the confining boxes.

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