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Two-Dimensional Rhombohedral Grid Coordination Polymers [M(bbbt) 2 (NCS) 2 ] n (M = Co, Mn, or Cd; bbbt = 1,1‘-(1,4-butanediyl) bis-1 H -benzotriazole): Synthesis, Crystal Structures, and Third-Order Nonlinear Optical Properties

✍ Scribed by Hou, Hongwei; Meng, Xiangru; Song, Yinglin; Fan, Yaoting; Zhu, Yu; Lu, Huijie; Du, Chenxia; Shao, Weihua

Book ID: 124078626
Publisher: American Chemical Society
Year: 2002
Tongue: English
Weight: 135 KB
Volume: 41
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic0255858

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A novel coordination polymer [Co(NCS)2(bpms)2]n (bpms=1,2-bis(4-pyridylmethyl)disulfenyl): synthesis, crystal structure and third-order nonlinear optical properties

✍ Hongwei Hou; Yinglin Song; Yaoting Fan; Linping Zhang; Chenxia Du; Yu Zhu 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 152 KB

A new 4,4%-bipyridyl-based 'building block', 1,2-bis(4-pyridylmethyl)disulfenyl (bpms) was synthesized. Treatment of the 'building block' with Co(NO 3 ) 2 and KSCN afforded a new type of one-dimensional (1-D) double zigzag chain coordination polymer [Co(NCS) 2 (bpms) 2 ] n . Each Co ion is symmetric