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Two-dimensional NMR spectra of sesquiterpenes. II—Noesy study of some sesquiterpene lactones with pseudoguaianolide, 3,4-seco-pseudoguaianolide and guaianolide skeletons

✍ Scribed by Ivana Aljančić-Šolaja; Slobodan Milosavljević; Miodrag Djermanović; Milutin Stefanović; Slobodan Macura


Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
368 KB
Volume
26
Category
Article
ISSN
0749-1581

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✦ Synopsis


The application of phase-sensitive 2 D 'H NOE NMR spectroscopy (PS NOESY) in the stereochemical assignment of sesquiterpene lactones such as 4-0~~3,4-seco-arnbrosan-6,120lide-3-oic acid methyl ester, 4-oxo-6hydroxypseudoguai-1 1( 13)-en-8,12-olide and &angeloyloxy-lO-acetoxyguai-3-en-6,12-olide is reported.