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Two-dimensional NMR analysis of the conformational and dynamic properties of .alpha.-helical poly(.gamma.-benzyl L-glutamate)

✍ Scribed by Mirau, Peter A.; Bovey, Frank A.


Book ID
126159292
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
648 KB
Volume
108
Category
Article
ISSN
0002-7863

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Solution properties of synthetic polypep
✍ Tadao Matsumoto; Akio Teramoto 📂 Article 📅 1974 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 567 KB

## Abstract The Zimm–Bragg parameters __s__ and σ were determined for poly(γ‐benzyl L‐glutamate) (PBLG) in __m__‐cresol and in dimethylformamide (DMF) from ORD data as a function of molecular weight. It was found that, within the temperature range between 10 and 55°C and on the average, __s__ = 1.6