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Two-dimensional inversion potential function for hydrazine determined from rotation—vibration spectra

✍ Scribed by Wiesław łodyga; Marek Krȩglewski

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 333 KB
Volume: 210
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)89137-7

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✦ Synopsis

The twodimensional potential function for inversion of the amino groups in hydrazine has been obtained from a fit to the available infrared and microwave data. The barriers of 3408 and 20 16 cm-' have been calculated for the symmetric and antisymmetric inversions of both amino groups, respectively. Contrary to earlier assumptions a large potential coupling between the inversions of the amino groups has been found.

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