The simple Hiickel molecular orbital theory is extended to include hydrocarbons with sp- hybridization in addition to the sp2-hybridization. Molecular orbitals are constructed as linear combinations of 2p orbitals in two dimensions perpendicular to each other. Total IT bond orders (P) are defined an
✦ LIBER ✦
Two-dimensional hückel molecular orbital theory
✍ Scribed by S.J. Cyvin
- Book ID
- 119115662
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 507 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0166-1280
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To achieve the selective population transfer to the specific excited state of molecules, the delayed-pulse method developed in the three-level system is more attractive and effective than the ordinary -pulses method. However, two pulses in this adiabatic method are in a counterintuitive order and ar