A method to generate the phase continuity necessary to perform broad-band two-dimensional Fourier transform ion cyclotron resonance (2D Ff/ICR) spectroscopy is proposed. This technique is used for studying ion-molecule reactions and multiphoton dissociation of ions in the gas phase. In a single two-
Two-dimensional fourier transform ion cyclotron resonance mass spectrometry
✍ Scribed by Peter Pfändler; Geoffrey Bodenhausen; Jacques Rapin; Raymond Houriet; Tino Gäumann
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 560 KB
- Volume
- 138
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Two-dimensional Fourier transform (2D FT) spectroscopy is applied to ion cyclotron resonance (ICR) to obtain direct evidence for mass transfer due to ion-molecule collisions. The 2D FI ICR experiment, which is closely analogous to 2D exchange NMR spectroscopy (NOESY), yields similar information to tandem mass spectroscopy (MS/MS), but could in principle be extended to study a manifold of mass-transfer processes simultaneously.
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