𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Two-dimensional Fourier-transform electron spin resonance in complex fluids

✍ Scribed by Sanghyuk Lee; Baldev R. Patyal; Sunil Saxena; Richard H. Crepeau; Jack H. Freed

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
945 KB
Volume
221
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

Two-dimensional Fourier-transform ESR spectra from a complex fluid characterized by very short free induction decay times are reported. They provide enhanced resolution to dynamic molecular structure compared to conventional cw-ESR spectra which are inhomogeneously broadened by the macroscopic disorder. A general theoretical analysis based on the stochastic Liouville equation permits us to accurately determine the microscopic ordering and motional dynamic rates by non-linear least-squares fitting to experiment.

πŸ“œ SIMILAR VOLUMES

Double quantum two-dimensional Fourier t
Double quantum two-dimensional Fourier transform electron spin resonance: Distance measurements
✍ Sunil Saxena; Jack H. Freed πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 746 KB

The first double quantum two-dimensional Fourier transform electron spin resonance (2D-ET ESR) experiments are reported. Extension of 2D-FT ESR to enable detection of the AM, = f2 transition enhances the capability of ESR in studying structural properties (i.e. distances in bilabeled molecules). A d

Absorption Lineshapes in Two-Dimensional
Absorption Lineshapes in Two-Dimensional Electron Spin Resonance and the Effects of Slow Motions in Complex Fluids
✍ Sunil Saxena; Jack H. Freed πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 540 KB

A methodology for obtaining pure absorption two-dimensional electron spin resonance spectra is presented for the case of large inhomogeneous broadening and/or slow motions. For slow motions, the spectra consist of "complex Lorentzians" superimposed with complex weighting factors, presenting a challe

A method to generate phase continuity in
A method to generate phase continuity in two-dimensional Fourier transform ion cyclotron resonance mass spectrometry
✍ Mike Bensimon; Guohong Zhao; Tino GΓ€umann πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 376 KB

A method to generate the phase continuity necessary to perform broad-band two-dimensional Fourier transform ion cyclotron resonance (2D Ff/ICR) spectroscopy is proposed. This technique is used for studying ion-molecule reactions and multiphoton dissociation of ions in the gas phase. In a single two-