✦ LIBER ✦
Two-dimensional 6Li, 1H heteronuclear Overhauser spectroscopy (HOESY) in magnitude and pure absorption representations. Application to a dimer–monomer equilibrium of a 1,4-dilithio compound
✍ Scribed by Walter Bauer; Paul Von Ragué Schleyer
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 541 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0749-1581
No coin nor oath required. For personal study only.
✦ Synopsis
Li, 'H HOESY was used both for the detection of short lithiurnproton distances and for proton spectral assignments of l,&ddithio-l,%diphenylhex-l-ene, which exists as a monomer-dimer equilibrium mixture in tetrahydrofuran (THF-d,). Experiments using magnitude mode, pure absorption and pseudo-steady-state mode representations are described. Pure absorption 'Li, 'H HOESY proved to be the superior method.