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Two-dimensional 29Si MAS n.m.r. investigation of the three-dimensional structure of zeolite DD3R

โœ Scribed by FYFE, C; GIES, H; FENG, Y; GRONDEY, H


Book ID
107894627
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
397 KB
Volume
10
Category
Article
ISSN
0144-2449

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Two-dimensional 29Si MAS NMR INADEQUATE experiments have been used to investigate the three-dimensional silicon bonding network in the monoclinic form of zeolite ZSM-5. Thirty-eight of the expected forty-eight Si-O-Si connectivities arc clearly observed, giving rise to two possible assignments of th

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Si MAS n.m.r. spectra are presented for highly siliceous samples of zeolites KZ-2,ZSM-12, and Beta. KZ-2 shows four resonances of relative intensities 2:1:1:2; ZSM-12, seven resonances of equal intensity; and Beta, a minimum of nine resonances of different intensities. The data are correlated with t