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Two different cyclization modes in the formation of silylhydrazines

✍ Scribed by Mitzel, Norbert W.; Bissinger, Peter; Riede, Juergen; Dreihaeupl, Karl Heinz; Schmidbaur, Hubert


Book ID
127335661
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
834 KB
Volume
12
Category
Article
ISSN
0276-7333

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In the hypothesis of illudoids' biosynthesis2, formation of the key intermediate protoilludyl cation&has been reasonably explained by the cationic cyclization of humulene, initiated at the 4 '\*lo double bond (Scheme I). However,