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Two crystalline modifications of Pd2(μ-ac)2(acac)2

✍ Scribed by S. P. Khranenko; E. A. Shusharina; S. A. Gromilov; S. V. Korenev


Book ID
110170578
Publisher
SP MAIK Nauka/Interperiodica
Year
2011
Tongue
English
Weight
239 KB
Volume
52
Category
Article
ISSN
0022-4766

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The reaction of [Me 2 SCH 2 C(O)CH 2 SMe 2 ]Br 2 (1) with Pd(OAc) 2 gives the mononuclear neutral complex cis- 2) through double deprotonation of the bis-sulfonium salt. The sulfur bisylide coordinates in (2) as a C,C 0 -chelating ligand, and is obtained as a single diastereoisomer (meso form, RS/SR