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Two consecutive cycloreversions of as-homobasketene (pentacyclo[5.4.0.02,5 03,9 04,8]undecene-10)

✍ Scribed by Wolfgang Mauer; Wolfram Grimme


Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
196 KB
Volume
17
Category
Article
ISSN
0040-4039

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✦ Synopsis


TWO CONSECUTIVE CYCLOREVEH5IONS OF' as-HOhiOB;2SKETE?iE -(t~ENT!~CYCL0[5.4,0.0?'5 O?*" 04~8]UXllECENE-10)


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Thermodynamic rearrangement of the penta
✍ Kata MlinariΔ‡-Majerski; Jelena VeljkoviΔ‡; Alan P. Marchand; Bishwajit Ganguly πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 375 KB

Reaction of Pentaeyclo[5.4.0.02,6.03'10.05'9] undecmle-8,l l-dione (l) with ethanedithiol, when performed in the presence of a Lewis acid catalyst (F3B-OEt2), afforded the corresponding mono(ethylene dithioacetal), 2, along with 7,8-[(thicethano)thio]pentacyclo[6.3.0.02,6.03, lO.05,9]undecan-l 1-on