Van der Waals complexes composed of naphthalene and triethylamine have been studied in free jet expansions by fluorescence excitation and resonance-enhanced two-photon ionization techniques. Intermolecular vibrational bands with frequencies of 8 and 40 cm-' appear to promote exciplex formation. The
Two-color photoionization of van der waals complexes of fluorobenzene in a supersonic free jet
β Scribed by Narishi Gonohe; Atsuo Shimizu; Haruo Abe; Naohiko Mikami; Mitsuo Ito
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 366 KB
- Volume
- 107
- Category
- Article
- ISSN
- 0009-2614
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Laser-induced fluorescence excitation spectroscopy in a supersonic expansion is used to evidence intermolecular chiral discrimination at the microscopic level. Measurements have been performed in (R)-(+)-and (S)-(-)-et-methyl-2-naphthalenemethanol (a naphthalene compound made chiral by the asymmetri
Laser-induced fluorescence spectra of Ne-and Ar-aniline complexes were observed with a resolution of 0.04 cm-l . By a simulation analysis of the rotational strucfures, the distances between the rare-gas atom and the aromatic ring of aniline were found fo be 3.35 f 0.04 and 3.50 + 0.04 4 in the X 'Al