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Two-center three-electron π-bonds in cyclic disulfide cation radicals

✍ Scribed by Kenji Morihashi; Seiichi Kushihara; Yuichi Inadomi; Osamu Kikuchi

Book ID
114142652
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
566 KB
Volume
418
Category
Article
ISSN
0166-1280

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Exceptionally Long (≥2.9 Å) CC Bonding I
Exceptionally Long (≥2.9 Å) CC Bonding Interactions in π-[TCNE]22− Dimers: Two-Electron Four-Center Cation-Mediated CC Bonding Interactions Involving π* Electrons
✍ Rico E. Del Sesto; Joel S. Miller; Pilar Lafuente; Juan J. Novoa 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 359 KB

Three groups of singlet ground state [TCNE](2) (2-) (TCNE=tetracyanoethylene) dimers with characteristic intradimer CC separations (r) and dihedral angles (d) [i.e., group S(t) (r approximately 1.6 A; d=180 degrees ), L(t) (r approximately 3.5 A; d=180 degrees ), and L(c) (r approximately 2.9 A; d=