Two-center overlap integrals in some acetylacetonates of f elements

✍ Scribed by Bogdan M. Angelov

• Publisher: Elsevier Science
• Year: 1975
• Tongue: English
• Weight: 411 KB
• Volume: 31
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(75)85072-x

✦ Synopsis

Overlap integrals of the type (2~10, (2~010 and t2pnlD have been evaluated for certain lanthanide and actinide awtvlacetonatei Slat&type orbit& with Bun& expone&, analytical Hartree-Fock Ivavefunctions and titeratomic distances taken from known crystal structure determinations of the same complexes have been used. The results indicate that the decreasing f-electron density with increasing atomic number predominate: over the corresponding contribution of the metal ion-oxygen distances.