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Twisted Intramolecular Charge Transfer States in 2-Arylbenzotriazoles: Fluorescence Deactivation via Intramolecular Electron Transfer Rather Than Proton Transfer

✍ Scribed by Maliakal, Ashok; Lem, George; Turro, Nicholas J.; Ravichandran, Ravi; Suhadolnik, Joseph C.; DeBellis, Anthony D.; Wood, Mervin G.; Lau, Jacqueline


Book ID
127288656
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
158 KB
Volume
106
Category
Article
ISSN
1089-5639

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Three competitive fluorescence emissions are shown to be observable from a common initial excited singlet state in a prototype aminosalicylate molecule: 2-hydroxy-4-dimethylaminobenzoic acid methyl ester. The fluorescences are assigned as the normal fluorescence S, (x, rr\*)-S,,, the twisted intramo