Dual fluorescence of 4dimethylaminobenzonitrile (DMABN) has been used to study the behavior of DMABN in a-cyclodextrine (a-CD). Results obtained indicate that DMABN in an aqueous a-CD solution probably exists in three different environmental conditions; polar, slightly polar and hydrophobic. DMABN s
Twisted intramolecular charge transfer emission of dimethylaminobenzonitrile in α-cyclodextrine cavities
✍ Scribed by Ashis Nag; Kankan Bhattacharyya
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 272 KB
- Volume
- 151
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The absorption and emission of 4-(N,N-dimethylarnino)benzonitrile (DMABN) in a-cyclodextrine (a-CD) cavities is reported. The twisted intramolecular charge transfer emission is enhanced on complexation with a-CD. This is attributed to the reduced polarity of the CD environment.
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