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Twin-SEDOR Spin-Warp Imaging of Low Gyromagnetic Ratio Nuclei

✍ Scribed by F. Deluca; G.H. Raza; M. Romeo; C. Casieri; B. Maraviglia


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
294 KB
Volume
107
Category
Article
ISSN
1064-1866

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✦ Synopsis


A 2D FT double-resonance imaging method for nuclei having a low gyromagnetic ratio is presented. The method is based on the twin-SEDOR pulse sequence that allows one to detect the signal only from the protons coupled to the rare nuclei by indirect interaction. The method was tested on boron-10-enriched (\mathrm{Na}{2} \mathrm{~B}{12} \mathrm{H}_{1} \mathrm{SH}) (BSH), in which the boron-10 played the role of the rare nucleus. The indirect imaging of the molecules containing boron- 10 is obtained with a signal-to-noise ratio given by the coupled protons and with an effective suppression of the solvent signal. (c) 1995 Academic Press, inc.