Tunnelling and reaction path curvature effects in the isomerization of the methoxy radical
β Scribed by Susan M. Colwell
- Book ID
- 104792099
- Publisher
- Springer
- Year
- 1988
- Tongue
- English
- Weight
- 588 KB
- Volume
- 74
- Category
- Article
- ISSN
- 1432-2234
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
By allowing dimethyl peroxide ( 10-4M) to decompose in the presence of nitric oxide (4.5 X lOW5M), nitrogen dioxide (6.5 X 10-5M) and carbon tetrafluoride (500 Torr), it has been shown that the ratio kzlkz, = 2.03 f 0.47: CH30 + NO -CH30NO (reaction 2) and CH30 + NO2 -CH30N02 (reaction 2'). Deviatio
## Abstract Various Cβcentered radicals can efficiently be generated through thermal Cο£ΏOβbond homolysis of alkoxyamines. This method is used to perform environmentally benign radical cyclization and intermolecular addition reactions. These alkoxyamine isomerizations and intermolecular carboaminoxyl