𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Tuning the Reversible Binding of NO to Iron(II) Aminocarboxylate and Related Complexes in Aqueous Solution

✍ Scribed by Thorsten Schneppensieper; Stefan Finkler; Almut Czap; Rudi van Eldik; Martin Heus; Peter Nieuwenhuizen; Carel Wreesmann; Wiebe Abma

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
716 KB
Volume
2001
Category
Article
ISSN
1434-1948

No coin nor oath required. For personal study only.

✦ Synopsis

Chelate complexes of Fe II were investigated with respect to their reactivity against nitric oxide and dioxygen. Through a systematic variation of the structure of the polyaminocarboxylate EDTA, a series of 38 potential chelate ligands were selected for Fe II . The nitrosyl complexes were prepared from the Fe II chelates with NO gas and examined spectroscopically by UV/Vis and ATR-IR techniques, and themodynamically by determining the overall binding constants for NO. In addition, the reversibility of NO binding to these Fe II chelates and the rate of the competing oxidation by dioxygen were studied qualitatively. Whereas the studied complexes all form more or less stable nitrosyl complexes with a characteristic band pattern in the UV/Vis spectra and only slightly diverging frequencies for the NO stretching vibration in the

πŸ“œ SIMILAR VOLUMES

Specific Chelate Tuning of the Substitut
Specific Chelate Tuning of the Substitution Kinetics of Platinum(II) Complexes in Aqueous Solution
✍ Ulrich Fekl; Rudi van Eldik πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 574 KB

## Both reaction steps observed for the substitution of water βˆ†V # = Οͺ5 cm 3 mol Οͺ1 . The temperature and pressure dependence of all the processes studied suggest an associative sub-by thiourea in the complexes [Pt(en)(OH 2 ) 2 ] 2+ and [Pt(phen)(OH 2 ) 2 ] 2+ (en = ethylenediamine, phen = 1,10-ph

Molecular configuration of amylose and i
Molecular configuration of amylose and its complexes in aqueous solutions. Part II. Relation between the DP of helical segments of the amylose–iodine complex and the equilibrium concentration of free iodine
✍ J. Szejtli; M. Richter; S. Augustat πŸ“‚ Article πŸ“… 1967 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 557 KB

## Synopsis The iodine which is added to an aqueoiis amylose solution is bound only partly by the amylose while forming the blue complex and partly remains free. The eqnilibriiim normality of the free and the bound iodine at half-saturation of amylose by iodine is designated as [I,], and respectiv