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Tuning the Energy Level and Photophysical and Electroluminescent Properties of Heavy Metal Complexes by Controlling the Ligation of the Metal with the Carbon of the Carbazole Unit

✍ Scribed by C. L. Yang; X. W. Zhang; H. You; L. Y. Zhu; L. Q. Chen; L. N. Zhu; Y. T. Tao; D. G. Ma; Z. G. Shuai; J. G. Qin

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
792 KB
Volume
17
Category
Article
ISSN
1616-301X

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## Abstract In the presence of Ni^2+^ the template reaction between 2,6‐diacetylpyridine and 4‐(2‐dimethylaminoethyl)‐ or 4‐(2‐hydroxyethyl)‐1, 7‐diamino‐4‐azaheptane yields the complexes of either the open‐chain ligand (**3** and **11**) or of the macrocycle (**4** and **12**). Reduction of the im