Tuning the Composition of Guest Molecules in Clathrate Hydrates: NMR Identification and Its Significance to Gas Storage

Dynamics of hydrogen molecules in the ch

Dynamics of hydrogen molecules in the channels of binary THF-H2 clathrate hydrate and its physicochemical significance on hydrogen storage

✍ Yong Nam Choi; J.M. Sungil Park; Thierry Strässle; Sun-Hwa Yeon; Youngjune Park; 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 438 KB

We have studied the dynamics of the H 2 loaded THF (tetrahydrofuran) clathrate hydrate by using an inelastic neutron scattering technique. At 2 K, a well defined single peak indicative of the ortho (J ¼ 1) to para (J ¼ 0) hydrogen transition is observed at 13.6 meV. The neutron spectrum undergoes tw