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Tuning the carrier concentration in organic conductors: Synthesis and physical properties of BEDT-TTF salts with H2PO4− and HPO42−

✍ Scribed by M. Kurmoo; D. Kanazawa; C.J. Kepert; P. Day


Book ID
116136050
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
169 KB
Volume
70
Category
Article
ISSN
0379-6779

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Bromohexyl)-3¢,4¢-ethylenedioxy)-2,2¢-bithiophene (3): Into a roundbottomed flask were introduced EDOT (5.9 g, 41.4 mmol) and 150 mL of tetrahydrofuran (THF). The mixture was cooled to ±40 C and butyllithium, 2.5 M in hexanes (19 mL, 47.5 mmol), was added rapidly. After 1 h stirring, tributyltin chl