Tunable far-infrared laser spectroscopy in a planar supersonic jet: The Σ bending vibration of ArH35Cl

✍ Scribed by Kerry L. Busarow; Geoffrey A. Blake; K.B. Laughlin; R.C. Cohen; Y.T. Lee; R.J. Saykally

• Publisher: Elsevier Science
• Year: 1987
• Tongue: English
• Weight: 208 KB
• Volume: 141
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(87)85025-x

✦ Synopsis

The lowest E bending vibration (02'0) of Ar-H"CI has been observed near 23.6 cm-' from P(23) to R(17), in a continuous planar jet expansion using a tunable far-infrared laser. A least-squares analysis has been performed to determine the centrifugal distortion constants for the ground and excited states, which will greatly facilitate the determination of an accurate intermolecular potential surface.