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Tunable Carbonyl Ylide Reactions: Selective Synthesis of Dihydrofurans and Dihydrobenzoxepines

✍ Scribed by Dr. Jiao-Long Zhou; Dr. Yong Liang; Chao Deng; Haolai Zhou; Zheng Wang; Dr. Xiu-Li Sun; Dr. Jun-Cheng Zheng; Prof. Dr. Zhi-Xiang Yu; Prof. Dr. Yong Tang

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
768 KB
Volume
50
Category
Article
ISSN
0044-8249

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ChemInform Abstract: Tunable Carbonyl Yl
ChemInform Abstract: Tunable Carbonyl Ylide Reactions: Selective Synthesis of Dihydrofurans and Dihydrobenzoxepines.
✍ Jiao-Long Zhou; Yong Liang; Chao Deng; Haolai Zhou; Zheng Wang; Xiu-Li Sun; Jun- 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 35 KB

## Abstract DFT calculations show, that the bulkiness of the ligand controls the reaction between α‐benzylidene‐β‐dicarbonyl compounds (I) and diazoacetate (II) to give either the five‐ or seven‐membered products (III)/(V) or (VI)/(VII).