Statistical thermodynamics of group inte
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Tsung-Wen Lee; Robert A. Greenkorn; Kwang-Chu Chao
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Article
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1973
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Elsevier Science
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English
⚖ 559 KB
The statistical thermodynamics previously developed for pure liquids of non-polar and polar chain molecules is extended to their mixtures. An orientation factor is introduced into the quasi-chemical relation of the hydrogen Bond to reduce the calculated preferential Bonding. Excess properties are ca