Trivalent nickel bis(triaza macrocyclic) complexes. Ligand ring size and medium effects on the nickel(III)/nickel(II) redox couple potential

Cooperative Effects in the Binding of Su

Cooperative Effects in the Binding of Substrates to Nickel(II) and Nickel(III) Complexes with a Bis(macrocyclic) Ligand

✍ Peter Comba; Yaroslaw D. Lampeka; Alexander Y. Nazarenko; Alexander I. Prikhod'k 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 258 KB 👁 2 views

Nickel(II) complexes of mono-and bis(macrocyclic) ligands are the products of a nickel(II)-assisted template reaction with 2,3,2-tet, melamine and formaldehyde [2,3,2-tet = bis-N,NЈ-(2-aminoethyl)propane-1,3-diamine; melamine = 2,4,6-triamino-1,3,5-triazine]. The structures of two four-coordinate, d