The mass spectral fragmentation of five pairs of 18g-and 18a-11-oxooleanolic acid derivatives la, 1b-5a, 5b are investigated and discussed. Fragmentation pathways, elucidation of which were assisted by accurate mass measurements and metastable transitions, are proposed. The obtained data create a sa
Triterpenoids. Part II—Carbon-13 NMR spectra of 18β- and 18α-11-oxooleanolic acid derivatives
✍ Scribed by U. Wrzeciono; L. Zaprutko; J. Budzianowski; H. Wojtowicz; D. Dubowska
- Publisher
- John Wiley and Sons
- Year
- 1987
- Tongue
- English
- Weight
- 313 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
The 13C NMR spectra of five pairs of 18p-and 18r~-ll-oxooleanolic acid derivatives have been assigned. The chemical shifts of C-12, C-13, C-17, C-18 and C-28 are of diagnostic value for the determination of the DIE junction stereochemistry. KEY WORDS "C NMR 18p-11 -oxooleanolic acid derivatives 18a-1 1 -oxooleanolic acid derivatives D/E ring junction ~ ~ ~ ~~ ~ Compounds C-12 C-13 C-16
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## Abstract The ^13^C NMR data of six pairs of 18α/18β‐glycyrrhetic acid derivatives are presented. It is shown that the configuration at C‐18 can easily be recognized by inspecting the chemical shifts of several characteristic carbons, e.g. C‐12, C‐13, C‐18 and C‐28. The shifts of these carbons or
The 13C NMR spectra of some pentacyclic triterpenoids, 3~-acetoxy-ll-oxo-olean-12-ene-30-oic acid methyl ester, 3~-acetoxy-ll-oxo-olean-12-ene-29-oic acid methyl ester, the corresponding 11-desoxo methyl esters, 3~-acetoxy-ll-oxo-18cw-olean-l2-en-30-oic acid methyl ester and 3~-acetoxy-ll-oxo-18~-ol
## Abstract ^13^C NMR signals were assigned for 18 methyl 5β‐cholenoates with a double bond in ring A, B, C or D (Δ^2^, Δ^3^, Δ^5^, Δ^6^, Δ^7^, Δ^8(14)^, Δ^9(11)^, Δ^11^ or Δ^14^). The double bond substituent effects on the ^13^C NMR chemical shifts of the parent 5β‐cholanoates were clarified.
## Abstract Complete assignments of ^1^H and ^13^C NMR chemical shifts for oleanolic acid, 18α‐oleanolic acid, ursolic acid and their 11‐oxo derivatives based on ^1^H, ^13^C, 2D DQF‐COSY, NOESY, HSQC, HMBC and HSQC‐TOCSY experiments were achieved. Copyright © 2003 John Wiley & Sons, Ltd.