Tris(trimethylsilyl)silane (TTMSS) : Formation of carbon-centered radicals from oxathiolane and thiazolidine derivatives

The Tris(trimethylsilyl)silane/Thiol Red

The Tris(trimethylsilyl)silane/Thiol Reducing System: A Tool for Measuring Rate Constants for Reactions of Carbon-Centered Radicals with Thiols

✍ Chryssostomos Chatgilialoglu 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 German ⚖ 125 KB

## Abstract An extension of the well‐known ‘free‐radical‐clock’ methodology is described that allows one to determine the rate constants of carbon‐centered radicals with a variety of thiols by using the tris(trimethylsilyl)silane/thiol couple as a reducing system. A total of 20 rate constants for t