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Tris(pyrazolyl)methanesulfonates: More Than Just Analogues of Tris(pyrazolyl)borate Ligands; N,N,N-, N,N,O-, and Other Coordination Modes

✍ Scribed by Wolfgang Kläui; Michael Berghahn; Walter Frank; Guido J. Reiß; Thomas Schönherr; Gerd Rheinwald; Heinrich Lang


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
253 KB
Volume
2003
Category
Article
ISSN
1434-1948

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Synthesis and Structure of [Tp*Rh{P(C7H7
✍ Max Herberhold; Stefan Eibl; Wolfgang Milius; Bernd Wrackmeyer 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 107 KB 👁 1 views

Stepwise introduction of the potential tripod ligands tris(3,5-dimethyl-1-pyrazolyl)borate (Tp\*) and tris(1cyclohepta-2,4,6-trienyl)phosphane into the coordination sphere of rhodium(I) leads mainly to [Tp\*Rh{P(C 7 H 7 ) 3 }] (4), in which Tp\* is linked to the rhodium through a single pyrazolyl gr