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Tris(polyoxaalkyl)amines (trident), a new class of solid-liquid phase-transfer catalysts

✍ Scribed by Soula, Gerard


Book ID
121481453
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
673 KB
Volume
50
Category
Article
ISSN
0022-3263

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Silicon polypodands 5-7 are found to be powerful complexing agents of alkali metal salts in low polarity solvents and very efficient catalysts in anion-promoted reactions under solid-liquid PTC conditions. The catalytic activity is comparable with that of the cyclic polyether PHDB18C6 8.