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Tris(5-methylpyrazolyl)methane: Synthesis and Properties of Its Iron(II) Complex

✍ Scribed by Goodman, Margaret A.; Nazarenko, Alexander Y.; Casavant, Barbara J.; Li, Zhanjie; Brennessel, William W.; DeMarco, Michael J.; Long, Gen; Goodman, M. Scott


Book ID
115446184
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
398 KB
Volume
51
Category
Article
ISSN
0020-1669

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## Abstract Treatment of anhydrous MCl~2~ (M = Mn, Fe) with (Ph~2~PMe~2~Si)~3~CH in toluene at elevated temperature resulted in the isolation of colorless (MnCl~2~{(Ph~2~PMe~2~Si)~3~CH}) (1) and light yellow (FeCl~2~{(Ph~2~PMe~2~Si)~3~CH}) (2) in high yield. These paramagnetic complexes have been c