Tris(2-pyridyl) tripod ligands
β Scribed by Lisa F Szczepura; Laura M Witham; Kenneth J Takeuchi
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 335 KB
- Volume
- 174
- Category
- Article
- ISSN
- 0010-8545
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π SIMILAR VOLUMES
Treatment of tris(2-pyridyl)phosphine or tris(2-pyridyl)phosphine oxide with electrophiles such as chlorine, bromine, deuterium chloride, or benzenediazonium chloride gave unusual coupling products, i.e., 5-chloro-, 5-bromo-, 5-deuterio-, or 5-phenylazo-2,2Πbipyridyls, respectively, as a major coupl
## The tripod ligands tris(2-diphenylphosphinoethyl)amine, np,, and tris(2-diphenylarsinoethyl)amine, ms3, form nickel(I) complexes having formulas Ni(np,)I and Ni(nas,)I. 7Fzese complexes have been studied by X-ray analysis, using diffractometric data. The two compounds are isomorphous, monoclinic,