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Tris (dipivalomethanato) ytterbium - induced shifts in PMR ketones and aldehydes

✍ Scribed by Z.W. Wolkowski


Book ID
104247493
Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
189 KB
Volume
12
Category
Article
ISSN
0040-4039

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Tris (dipivalomethanato) europium - indu
✍ Z.W. Wolkowski πŸ“‚ Article πŸ“… 1971 πŸ› Elsevier Science 🌐 French βš– 169 KB

Proton magnetic resonance has revealed itself as a method of choice in the investigation of isomeric oximes, since the anisotropy of the hydroxyimino group determines large chemical shift differences between syn and anti protons (1). Positive results in assignment by PMR have also been obtained from

Quantitation of the chemical shifts indu
✍ Anthony F. Cockerill; David M. Rackham πŸ“‚ Article πŸ“… 1970 πŸ› Elsevier Science 🌐 French βš– 220 KB

Like Wahl and Peterson,' we have recently used the NMR shift reagent, tris(dipivalomethanato)europium III [Eu(dpm)JZp3 to simplify the spectra of 2-hydroxyadamantane and in addition we have also studied a variety of I-R-adamantanes(R = (CH2),CH, n= 1, 2, 3) and cyclopentanol. Wahl and Peterson have

Application of paramagnetic induced shif
✍ Kazuo Tori; Yohko Yoshimura; Ryōnosuke Muneyuki πŸ“‚ Article πŸ“… 1971 πŸ› Elsevier Science 🌐 French βš– 178 KB

## Applications of pammagnetic induced shifts of metal complexes (1) in PMR spectm to structure determinations of organic molecules (2) have recently been highlighted by Hinckley's discovery of tris(dipivalomethanato)bis(pyrIdino)europiun(III) [ Eu(DPM)a\*Pyz 1 as a shift reagent (3); thereafter,